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Polydimethylsiloxane assisted supercritical CO

Weixia Wang, Shuai Zhou, Zhong Xin, Yaoqi Shi, Shicheng Zhao

《化学科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 396-404 doi: 10.1007/s11705-016-1577-z

摘要： Foamable high melt strength polypropylene (HMSPP) was prepared by grafting styrene (St) onto polypropylene (PP) and simultaneously introducing polydimethylsiloxane (PDMS) through?a?one-step?melt extrusion process. The effect of PDMS viscosity on the foaming behavior of HMSPP was systematically investigated using supercritical CO as the foaming agent. The results show that the addition of PDMS has little effect on the grafting reaction of St and HMSPP exhibits enhanced elastic response and obvious strain hardening effect. Though the CO solubility of HMSPP with PDMS (PDMS-HMSPP) is lower than that of HMSPP without PDMS, especially for PDMS with low viscosity, the PDMS-HMSPP foams exhibit narrow cell size distribution and high cell density. The fracture morphology of PDMS-HMSPP shows that PDMS with low viscosity disperses more easily and uniformly in HMSPP matrix, leading to form small domains during the extrusion process. These small domains act as bubble nucleation sites and thus may be responsible for the improved foaming performance of HMSPP.

关键词： high melt strength polypropylene (HMSPP)     polydimethylsiloxane (PDMS)     supercritical CO2     foaming behavior    

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Dispersion of a novel phenolic rigid organic filler in isotactic polypropylene matrix by solution-mixingand melt-mixing

Dongming QI, Xiaoli ZHAO, Zhijie CHEN, Peng HUANG, Jun CAO

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 395-402 doi: 10.1007/s11705-012-1269-2

摘要： A novel phenolic rigid organic filler (named KD) with a high melting point was dispersed in an isotactic polypropylene (iPP) matrix by solution-mixing and/or melt-mixing. A series of KD/iPP blends was prepared with or without addition of maleic anhydride-grafted polypropylene (MAPP) as a compatibilizer. Influences of MAPP and mixing methods on the filler dispersion were studied using polaried optical microscope (POM), scanning electron microscope (SEM) and tensile test. The filler particles are always inclined to form large irregular aggregates in the iPP matrix due to their significant differences in polarity and solubility in solvent. However, an iPP/MAPP/KD (PMK) blend containing filler particles with a quasi-spherical shape (~97.8 nm in diameter) and narrow particle size distribution (polydispersity index= 1.076) was successfully prepared by incorporating MAPP to reduce the interfacial tension and surface free energy between the dispersion phase and the continuous phase, and adopting a spray-drying method after solution-mixing to suppress the increase of the size of the dispersed phase during the removal of solvent.

关键词： dispersion     rigid organic filler     isotactic polypropylene     mixing    

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Optimizing the compressive strength of concrete containing micro-silica, nano-silica, and polypropylene

Fatemeh ZAHIRI, Hamid ESKANDARI-NADDAF

《结构与土木工程前沿（英文）》 2019年 第13卷 第4期   页码 821-830 doi: 10.1007/s11709-019-0518-6

摘要： Many studies have evaluated the effects of additives such as nano-silica (NS), micro-silica (MS) and polymer fibers on optimizing the mechanical properties of concrete, such as compressive strength. Nowadays, with progress in cement industry provides, it has become possible to produce cement type I with strength classes of 32.5, 42.5, and 52.5 MPa. On the one hand, the microstructure of cement has changed, and modified by NS, MS, and polymers; therefore it is very important to determine the optimal percentage of each additives for those CSCs. In this study, 12 mix designs containing different percentages of MS, NS, and polymer fibers in three cement strength classes(CSCs) (32.5, 42.5, and 52.5 MPa) were designed and constructed based on the mixture method. Results indicated the sensitivity of each CSCs can be different on the NS or MS in compressive strength of concrete. Consequently, strength classes have a significant effect on the amount of MS and NS in mix design of concrete. While, polymer fibers don’t have significant effect in compressive strength considering CSCs.

关键词： mixture method     compressive strength     nano-silica     micro-silica     polypropylene fibers    

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Exploring the mechanical properties of steel- and polypropylene-reinforced ultra-high-performance concrete

《结构与土木工程前沿（英文）》   页码 1228-1248 doi: 10.1007/s11709-023-0931-8

摘要： This study presents experimental and numerical investigations on the mechanical properties of ultra-high-performance concrete (UHPC) reinforced with single and hybrid micro- and macro-steel and polypropylene fibers. For this purpose, a series of cubic, cylindrical, dog-bone, and prismatic beam specimens (total fiber by volume = 1%, and 2%) were tested under compressive, tensile, and flexural loadings. A method, namely multi-target digital image correlation (MT-DIC) was used to monitor the displacement and deflection values. The obtained experimental data were subsequently used to discuss influential parameters, i.e., flexural strength, tensile strength, size effect, etc. Numerical analyses were also carried out using finite element software to account for the sensitivity of different parameters. Furthermore, nonlinear regression analyses were conducted to obtain the flexural load-deflection curves. The results showed that the MT-DIC method was capable of estimating the tensile and flexural responses as well as the location of the crack with high accuracy. In addition, the regression analyses showed excellent consistency with the experimental results, with correlation coefficients close to unity. Furthermore, size-effect modeling revealed that modified Bazant theory yielded the best estimation of the size-effect phenomenon compared to other models.

关键词： UHPC     MT-DIC     flexural behavior     tensile behavior     steel fiber     polypropylene fiber    

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Slender reinforced concrete shear walls with high-strength concrete boundary elements

《结构与土木工程前沿（英文）》 2023年 第17卷 第1期   页码 138-151 doi: 10.1007/s11709-022-0897-y

摘要： Reinforced concrete structural walls are commonly used for resisting lateral forces in buildings. Owing to the advancements in the field of concrete materials over the past few decades, concrete mixes of high compressive strength, commonly referred to as high-strength concrete (HSC), have been developed. In this study, the effects of strategic placement of HSC on the performance of slender walls were examined. The finite-element model of a conventional normal-strength concrete (NSC) prototype wall was validated using test data available in extant studies. HSC was incorporated in the boundary elements of the wall to compare its performance with that of the conventional wall at different axial loads. Potential reductions in the reinforcement area and size of the boundary elements were investigated. The HSC wall exhibited improved strength and stiffness, and thereby, allowed reduction in the longitudinal reinforcement area and size of the boundary elements for the same strength of the conventional wall. Cold joints resulting from dissimilar concrete pours in the web and boundary elements of the HSC wall were modeled and their impact on behavior of the wall was examined.

关键词： slender walls     high-strength concrete     rectangular and barbell-shaped walls     cold joints    

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Data driven models for compressive strength prediction of concrete at high temperatures

Mahmood AKBARI, Vahid JAFARI DELIGANI

《结构与土木工程前沿（英文）》 2020年 第14卷 第2期   页码 311-321 doi: 10.1007/s11709-019-0593-8

摘要： The use of data driven models has been shown to be useful for simulating complex engineering processes, when the only information available consists of the data of the process. In this study, four data-driven models, namely multiple linear regression, artificial neural network, adaptive neural fuzzy inference system, and nearest neighbor models based on collection of 207 laboratory tests, are investigated for compressive strength prediction of concrete at high temperature. In addition for each model, two different sets of input variables are examined: a complete set and a parsimonious set of involved variables. The results obtained are compared with each other and also to the equations of NIST Technical Note standard and demonstrate the suitability of using the data driven models to predict the compressive strength at high temperature. In addition, the results show employing the parsimonious set of input variables is sufficient for the data driven models to make satisfactory results.

关键词： data driven model     compressive strength     concrete     high temperature    

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Flexural behavior of high-strength, steel-reinforced, and prestressed concrete beams

Qing JIANG, Hanqin WANG, Xun CHONG, Yulong FENG, Xianguo YE

《结构与土木工程前沿（英文）》 2021年 第15卷 第1期   页码 227-243 doi: 10.1007/s11709-020-0687-3

摘要： To study the flexural behavior of prestressed concrete beams with high-strength steel reinforcement and high-strength concrete and improve the crack width calculation method for flexural components with such reinforcement and concrete, 12 specimens were tested under static loading. The failure modes, flexural strength, ductility, and crack width of the specimens were analyzed. The results show that the failure mode of the test beams was similar to that of the beams with normal reinforced concrete. A brittle failure did not occur in the specimens. To further understand the working mechanism, the results of other experimental studies were collected and discussed. The results show that the normalized reinforcement ratio has a greater effect on the ductility than the concrete strength. The cracking- and peak-moment formulas in the code for the design of concrete (GB 50010-2010) applied to the beams were both found to be acceptable. However, the calculation results of the maximum crack width following GB 50010-2010 and EN 1992-1-1:2004 were considerably conservative. In the context of GB 50010-2010, a revised formula for the crack width is proposed with modifications to two major factors: the average crack spacing and an amplification coefficient of the maximum crack width to the average spacing. The mean value of the ratio of the maximum crack width among the 12 test results and the relative calculation results from the revised formula is 1.017, which is better than the calculation result from GB 50010-2010. Therefore, the new formula calculates the crack width more accurately in high-strength concrete and high-strength steel reinforcement members. Finally, finite element models were established using ADINA software and validated based on the test results. This study provides an important reference for the development of high-strength concrete and high-strength steel reinforcement structures.

关键词： high-strength steel reinforcement     high-strength concrete     flexural behavior     crack width    

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A numerical study of prestressed high strength steel tubular members

Michaela GKANTOU, Marios THEOFANOUS, Charalampos BANIOTOPOULOS

《结构与土木工程前沿（英文）》 2020年 第14卷 第1期   页码 10-22 doi: 10.1007/s11709-019-0547-1

摘要： The structural behavior of prestressed high strength steel (HSS) tubular members is investigated through the execution of advanced finite element modeling. Numerical models are developed and validated against published experimental data on HSS tubular members subjected to different levels of initial prestress and loaded either in tension or compression. The effect of the presence or absence of grouting on the strength and ductility of the members is also considered. To numerically replicate the structural response recorded in the tests, some key modeling features including the employed numerical solver, the adopted material models and the element types warrant careful consideration. Upon developing of the finite element models, the numerically generated ultimate loads, the corresponding failure modes and the full load-deformation curves are compared to the experimental ones, indicating a successful validation. As anticipated, prestressing enhances the load-bearing capacity for the tensile members, whereas it is detrimental for the compressive ones. A series of parametric studies is performed to assess the influence of key factors on the structural response of prestressed HSS members and the obtained results are discussed. Design guidance for tensile and compressive prestressed tubular members is also provided.

关键词： finite element     prestressing     tubular members     grout     high strength steel    

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Calculation methods of the crack width and deformation for concrete beams with high-strength steel bars

Jianmin ZHOU, Shuo CHEN, Yang CHEN

《结构与土木工程前沿（英文）》 2013年 第7卷 第3期   页码 316-324 doi: 10.1007/s11709-013-0211-0

摘要： Three groups of concrete beams reinforced with high-strength steel bars were tested, and the crack width and deformation of the specimens were observed and studied. To facilitate the predictions, two simplified formulations according to a theory developed by the first author were proposed. The advantages of the formulations were verified by the test data and compared with several formulas in different codes.

关键词： concrete beam     high-strength steel bar     crack width     deformation    

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Utilizing melt crystallization fundamentals in the development of a new tabletting technology

Ahmed ABOUZEID,Sandra PETERSEN,Joachim ULRICH

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 346-352 doi: 10.1007/s11705-014-1443-9

摘要： Increasing production effeciency and lowering costs are some of the many advantages melt crystallization technology offers over the conventional methodology of tabletting. A normal tablet consists of a pure shell or a coat and a separate core constituting the pharmaceutical active ingredient. Great emphasis is put on the purity of the shell since its purpose is to solely protect and deliver the active ingredient to its target. Melt crystallization is a purification (separation) process. It is discussed here for its ability to produce coated tablets, by separating the “coating” material from the “to be coated” material coming from one molten mixture. Molten drops of lutrol-ibuprofen mixture are produced using the drop forming technique. The subsequent analysis involves proving and quantifying the phase separation (coat purity). The mechanism of a crystallizing drop is shown as direct evidence of the ongoing process. Moreover, solidified tablet batches are analyzed for the purity of their coating by measuring the ibuprofen concentration. This optimization process is carried out through multiple stages of development and condition enhancements in order to produce the most pure tablet coating. As a result, a trial showing an almost purely coated tablet is presented here.

关键词： phase separation     melt crystallization     tablets     process optimization    

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An experimental study on the flexural behavior of heavily steel reinforced beams with high-strength concrete

Yasser SHARIFI, Ali Akbar MAGHSOUDI

《结构与土木工程前沿（英文）》 2014年 第8卷 第1期   页码 46-56 doi: 10.1007/s11709-014-0237-y

摘要： In recent years, an emerging technology termed high-strength concrete (HSC) has become popular in construction industry. Present study describes an experimental research on the behavior of high-strength concrete beams in ultimate and service state. Six simply supported beams were tested, by applying comprising two symmetric concentrated loads. Tests are reported in this study on the flexural behavior of high-strength reinforced concrete (HSRC) beams made with coarse and fine aggregate together with Microsilica. Test parameter considered includes effect of being compressive reinforcement. Based on the obtained results, the behavior of such members is more deeply reviewed. Also a comparison between theoretical and experimental results is reported here. The beams were made from concrete having compressive strength of 66.81–77.72 N/mm and percentage reinforcement ratio ( / ) in the range of 0.56% – 1.20%. The ultimate moment for the tested beams was found to be in a good agreement with that of the predicted ultimate moment based on ACI 318-11, ACI 363 and CSA-04 provisions. The predicted deflection based classical formulation based on code provisions for serviceability requirements is found to underestimate the maximum deflection of HSC reinforced beams at service load.

关键词： high-strength concrete (HSC) members     flexural behavior     reinforced concrete     experimental results     ultimate moment    

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State-of-the-art on resistance of bearing-type bolted connections in high strength steel

Guoqiang LI, Yifan LYU, Yanbo WANG

《结构与土木工程前沿（英文）》 2020年 第14卷 第3期   页码 569-585 doi: 10.1007/s11709-020-0607-6

摘要： With the recent development of material science, high strength steel (HSS) has become a practical solution for landmark buildings and major projects. The current codes for design of bearing-type bolted connections of steel constructions were established based on the research of conventional steels. Since the mechanical properties of HSS are different from those of conventional steels, more works should be done to develop the appropriate approach for the design of bearing-type bolted connections in HSS. A review of the research carried out on bearing-type bolted connections fabricated from conventional steel and HSS is presented. The up-to-date tests conducted at Tongji University on four connection types fabricated from three grades of HSS with nominal yield strengths of 550, 690, and 890 MPa are presented. The previous research on failure modes, bearing resistance and the design with consideration of bolt hole elongation are summarized. It is found that the behavior of bolted connections in HSS have no drastic difference compared to that of conventional steel connections. Although the ductility is reduced, plastic deformation capacity of HSS is sufficient to ensure the load redistribution between different bolts with normal construction tolerances. It is also found that behavior of each bolt of multi-bolt connections arranged in perpendicular to load direction is almost identical to that of a single-bolt connection with the same end distance. For connections with bolts arranged in parallel to load direction, the deformation capacity of the whole connection depends on the minimum value between the end distance and the spacing distances in load direction. The comparison with existing design codes shows that Eurocode3 and Chinese GB50017-2017 are conservative for the design of bolted connections in HSS while AISC 360-16 may overestimate the bearing resistance of bolted connections.

关键词： High strength steel     bolted connection     bearing behavior     design codes    

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Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength

Shivang D. JAYSWAL; Mahesh MUNGULE

《结构与土木工程前沿（英文）》 2022年 第16卷 第5期   页码 576-588 doi: 10.1007/s11709-022-0826-0

摘要： Previous studies on concrete have identified silica fume (SF) as the most effective supplementary material, whereas fly ash (FA) and slag have been identified as economical materials with long term strength potential. Development of blended cement mortar referred to as blended mortar (BM) requires similar assessment. The present study explores the application of Alccofine (AL) as supplementary material and compares its performance with conventional materials namely SF, FA and ground granulated blast furnace slag (GGBS). The mortar specimens with binder to fine-aggregates (b/f ) ratio of 1:2 are prepared at water to binder (w/b) ratios of 0.4 and 0.35. The strength values and stress-strain curve for control and BM specimens are obtained at 7, 28, 56, and 90 d curing periods. The assessment based on strength activity index, k-value method and strength estimation model confirms that AL, despite lower pozzolanic activity, contributes to strength gain, due to reduced dilution effect. Assessment of stress-strain curves suggests that the effect of w/b ratio is more dominant on the elastic modulus of BM specimens than on control specimens. The observations from the study identify enhanced strength gain, improved elastic modulus and higher energy absorption as key contributions of AL making it a potential supplementary material.

关键词： Alccofine     high strength mortar     efficiency factor     dilution effect    

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Development of lunar regolith-based composite for - 3D printing via high-pressure extrusion system

《机械工程前沿（英文）》 2023年 第18卷 第2期 doi: 10.1007/s11465-022-0745-8

摘要： To fully utilize the in-situ resources on the moon to facilitate the establishment of a lunar habitat is significant to realize the long-term residence of mankind on the moon and the deep space exploration in the future. Thus, intensive research works have been conducted to develop types of 3D printing approach to adapt to the extreme environment and utilize the lunar regolith for in-situ construction. However, the in-situ 3D printing using raw lunar regolith consumes extremely high energy and time. In this work, we proposed a cost-effective melting extrusion system for lunar regolith-based composite printing, and engineering thermoplastic powders are employed as a bonding agent for lunar regolith composite. The high-performance nylon and lunar regolith are uniformly pre-mixed in powder form with different weight fractions. The high-pressure extrusion system is helpful to enhance the interface affinity of polymer binders with lunar regolith as well as maximize the loading ratio of in-situ resources of lunar regolith. Mechanical properties such as tensile strength, elastic modulus, and Poisson’s ratio of the printed specimens were evaluated systematically. Especially, the impact performance was emphasized to improve the resistance of the meteorite impact on the moon. The maximum tensile strength and impact toughness reach 36.2 MPa and 5.15 kJ/m2, respectively. High-pressure melt extrusion for lunar regolith composite can increase the effective loading fraction up to 80 wt.% and relatively easily adapt to extreme conditions for in-situ manufacturing.

关键词： in-situ resource utilization     melt extrusion molding     lunar regolith-based composites     mechanical properties     additive manufacturing    

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Behavior and strength of headed stud shear connectors in ultra-high performance concrete of composite

Jianan QI, Yuqing HU, Jingquan WANG, Wenchao LI

《结构与土木工程前沿（英文）》 2019年 第13卷 第5期   页码 1138-1149 doi: 10.1007/s11709-019-0542-6

摘要： This study presents an experimental and numerical investigation on the static behavior of headed stud shear connectors in ultra-high performance concrete (UHPC) of composite bridges. Four push-out specimens were tested. It was found that no cracking, crushing or splitting was observed on the concrete slab, indicating that UHPC slab exhibited good performance and could resist the high force transferred from the headed studs. The numerical and experimental results indicated that the shear capacity is supposed to be composed of two parts stud shank shear contribution and concrete wedge block shear contribution. The stiffness increment of a stud in UHPC was at least 60% higher than that in normal strength concrete. Even if the stud height was reduced from 6 to 2 , there was no reduction in the shear strength of a stud. Short stud shear connectors with an aspect ratio as small as 2 could develop full strength in UHPC slabs. An empirical load-slip equation taking into account stud diameter was proposed to predict the load-slip response of a stud. The reliability and accuracy of the proposed load-slip equation was verified by the experimental and numerical load-slip curves.

关键词： ultra-high performance concrete     studs     shear strength     FE analysis     push-out test    

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标题 作者 时间 类型 操作

Polydimethylsiloxane assisted supercritical CO

Weixia Wang, Shuai Zhou, Zhong Xin, Yaoqi Shi, Shicheng Zhao

期刊论文

Dispersion of a novel phenolic rigid organic filler in isotactic polypropylene matrix by solution-mixingand melt-mixing

Dongming QI, Xiaoli ZHAO, Zhijie CHEN, Peng HUANG, Jun CAO

期刊论文

Optimizing the compressive strength of concrete containing micro-silica, nano-silica, and polypropylene

Fatemeh ZAHIRI, Hamid ESKANDARI-NADDAF

期刊论文

Exploring the mechanical properties of steel- and polypropylene-reinforced ultra-high-performance concrete

期刊论文

Slender reinforced concrete shear walls with high-strength concrete boundary elements

期刊论文

Data driven models for compressive strength prediction of concrete at high temperatures

Mahmood AKBARI, Vahid JAFARI DELIGANI

期刊论文

Flexural behavior of high-strength, steel-reinforced, and prestressed concrete beams

Qing JIANG, Hanqin WANG, Xun CHONG, Yulong FENG, Xianguo YE

期刊论文

A numerical study of prestressed high strength steel tubular members

Michaela GKANTOU, Marios THEOFANOUS, Charalampos BANIOTOPOULOS

期刊论文

Calculation methods of the crack width and deformation for concrete beams with high-strength steel bars

Jianmin ZHOU, Shuo CHEN, Yang CHEN

期刊论文

Utilizing melt crystallization fundamentals in the development of a new tabletting technology

Ahmed ABOUZEID,Sandra PETERSEN,Joachim ULRICH

期刊论文

An experimental study on the flexural behavior of heavily steel reinforced beams with high-strength concrete

Yasser SHARIFI, Ali Akbar MAGHSOUDI

期刊论文

State-of-the-art on resistance of bearing-type bolted connections in high strength steel

Guoqiang LI, Yifan LYU, Yanbo WANG

期刊论文

Performance assessment of Alccofine with silica fume, fly ash and slag for development of high strength

Shivang D. JAYSWAL; Mahesh MUNGULE

期刊论文

Development of lunar regolith-based composite for - 3D printing via high-pressure extrusion system

期刊论文

Behavior and strength of headed stud shear connectors in ultra-high performance concrete of composite

Jianan QI, Yuqing HU, Jingquan WANG, Wenchao LI

期刊论文